Sunday, June 2, 2019

Intermolecular hydrogen bond

Intermolecular hydrogen bonds occur between two separate molecules. They can occur between any numbers of molecules as long as hydrogen donors and acceptors are present in the positions which enable the hydrogen bonding interactions. For example, intermolecular hydrogen bonds can occur between ammonia molecule themselves or between  water molecules themselves or between ammonia and water. Water molecules form strong hydrogen bonds with one another. For example, each water molecule is linked to four others through hydrogen bonds. The shorter distances  correspond to covalent bonds, and the longer distances correspond to hydrogen bonds. In ice, each atom is surrounded tetrahedrally by four water molecules through hydrogen bonds. That is, the presence of two hydrogen atoms and two lone pairs of electron on oxygen atoms in each water molecule allows formation of a three-dimensional structure. This arrangement creates an open structure, which accounts for the lower density of ice compared with water at 0°C. While in liquid water, unlike ice where hydrogen bonding occurs over a long-range, the strong hydrogen bonding prevails only in a short range and therefore the denser packing.



Reference: cbseportal.com

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